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Silica Gel

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Molecular Sieve

What Are Zeolite Molecular Sieves?

Zeolite molecular sieves are crystalline structures that, on a molecular scale, are not unlike sponges. They have a solid framework, defined by large internal cavities where molecules can be adsorbed. These cavities are interconnected by pore openings through which molecules can pass, and because of their crystalline nature, the pores and cavities are all precisely the same size. Depending on the size of the openings, they can adsorb molecules readily, slowly, or not at all, thus functioning as molecular sieves -- adsorbing molecules of certain sizes while rejecting larger ones.

The ability of these molecular sieves to attract and sort molecules is also affected by the electrical charge or polarity of the molecules being sorted. Synthetic zeolites possess the unique ability to selectively adsorb molecules by size and polarity. This is the key to their unusual efficiency as agents for drying and purifying liquids and gases. Such abilities also serve as the basis for separation.

Synthetic zeolites can be manufactured to provide a wide range of desired adsorption characteristics or selectivities, and can be used as a separation tool for numerous commercial applications.

Traditional molecular sieves work as desiccants, adsorbents, and ion exchangers. UOP also offers high silica zeolites for non-traditional applications, including the removal of organic bodies that can cause odors or affect taste within food and beverage packaging

Molecular sieves have selective adsorption,that is to say it will absorb the moleculars of which the diameter is less than the pore size of molecular sieve. As for polar moleculars and unsaturated moleculs, Molecular sieves have selective adsorption. The bigger the polarity .the higher unsaturated ratio, the stronger selective adsorption. Molecular sieves have high water absorption even in high temperature, large space velocity or low content of water, it has quite a higher water absorption capacity.
molecular sieve are divided into several types of 3A, 4A, 5A, 13X, IG Desiccant, 13XAPG, Refrigerant Desiccant according to its use.

3A Molecular Sieve

Typical applications:

  • Dehydration of many kinds of liquids (such as ethanol)
  • Dehydration of air
  • Dehydration of refrigerant
  • Dehydration of natural gas or methane
  • Dehydration of cracked gas, ethylene, propylene or butadiene

13X Molecular Sieve

Introduction
The pore size for 13X molecular sieve is about 10A. It can adsorb any molecular smaller than 10A, mainly used as catalyze carrier, co adsorption of CO2 and H2O and H2O, H2O and H2S, as a desiccant for medical and air compressor systems, and can also be adjusted to fit other various applications.

Typical applications:

  • Purification and removal of H2O and CO2
  • Dehydration and desulfuration of nature gas, liquid petro gas and liquid alkane
  • Drying of common gases

13X APG mol seive

Introduction
Type 13X APG molecular sieve is specially designed to co-absorb CO2 and H2O for air cryo-separation industry. It has larger capacity and faster adsorption speed for removal of CO2 and H2O to prevent the bed gelation, it is suitable for any air cryo-separation plants of any size and any types in the world.

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PSA O2 HP MOLSIV™ ADSORBENT

Introduction
PSA O2 HP adsorbent was specifically developed for on-site generation of oxygen in super-atmospheric pressure swing cycles. The nitrogen selectivity of the product makes it particularly applicable for this function.
PSA O2 HP molecular sieve can also be used to retrofit PSA O2 units containing older generation adsorbents to increase productivity or to reduce power consumption.

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What Are Aluminas?

Introduction

Aluminas are a family of aluminum oxides (Al2O3) that can take many forms. As a general term, “alumina” refers to the lower temperature transition alumina forms. The most common use for aluminas is in the manufacturing of aluminum, a metal commonly used in beverage cans, automobiles, and many other applications where a lightweight, durable metal is required. UOP manufactures and markets two unique aluminas for use as adsorbents and catalysts, as well as numerous other applications.

Activated aluminas are both high surface area beads and crushed products that are “activated” by a proprietary process to achieve specific surface chemistry and reactivity. Commonly used as adsorbents, desiccants and catalysts, the chemistry, size and structure of these aluminas are tailored to specific applications at UOP’s ISO 9001:2000 certified plant in Baton Rouge, Louisiana. Additives are also commonly used with activated aluminas to achieve even greater performance in certain markets.

Versal aluminas are a family of high purity alumina powders available in a variety of rheological and physical forms. They are used primarily as catalyst supports, washcoat slurries, and binders. Their many forms and uses have led us to name this versatile group of alumina products “VERSAL.”

The forerunner of the Versal alumina line was the “gel” alumina, a name which referred to the colloidal state of the powders. Through our ongoing alumina development, UOP has expanded this array to include pseudoboehmite, gamma and bayerite aluminas, all with varying densities and dispersibility ranges. In addition to being a key component in many commonly used catalysts, UOP’s Versal aluminas are also used as adsorbents. They also play key roles in the polishing, abrasives and surface coatings industries.

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Insulating Glass Desiccant

Introduction
Insulating glass desiccant deeply co-adsorbs the resident moisture and organics in Insulating Glass and keeps the IG clear and transparent even at very low temperatures. More importantly, it can successfully prevent the distortions from air pressure changes placed on the glass thru the changing of the day-night temperatures. It carries this out by thru desorption and adsorption to maintain a constant air pressure. This resolves the problem of windows distortion caused by IG expansion and shrinkage, preserving the life span of IG windows.

Carbon Molecular Sieve

Introduction
The component of carbon molecular sieve (CMS) is carbon. CMS takes the appearance of cylindrical black solid, contains countless 4 angstrom fine pores, it can be used to separate air into nitrogen and oxygen .In industry, CMS can concentrate nitrogen from air with PSA systems. Our CMS products have the character of large nitrogen yield capacity; high nitrogen recovery. It can meet the requirement of all types of PSA nitrogen systems.

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Catalyst support Ceramic Balls

Having stable chemical features and a low rate of water absorption, Inert Alumina ceramic balls can resist high temperatures and high pressure. Inert Alumina ceramic balls can also resist the corrosion of acid, alkali and some other organic solvents, Inert Alumina ceramic balls are able to stand the thermal shock (quick change of temperature) during the manufacturing process. The main role of these Inert Alumina ceramic balls is to increase the distribution spots of gas or liquid, and to support and protect the activating catalyst of low strength in the reactors and column/tower.

Applications:
As refractory bed top plugs and supports in order to protect the catalyst bed from thermal impurities so that the catalyst bed is kept intact in spite of wide pressure variation. Inert Aluminum Ceramic Balls are widely used in petrochemical industry, chemical industry, fertilizer industry, natural gas industry and environment protection, etc.

Stoneware Catalyst Bed Supports are used routinely in the following specific services: Ammonia plants, Hydrotreaters, Bender treaters, Isomerization units, Chloride absorbers, pretreaters and reactors, Claus units, Molecular sieve units, Diesel hydrotreaters, Naphtha treaters, Fixed bed reformers, Reformer pretreaters, Fluidized pollution control, Hydrocrackers (1st stage), VGO pretreaters, Hydrogen plants.

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